Main Group Chemistry / Edition 1

Main Group Chemistry / Edition 1

ISBN-10:
0854046178
ISBN-13:
9780854046171
Pub. Date:
08/04/2000
Publisher:
RSC
ISBN-10:
0854046178
ISBN-13:
9780854046171
Pub. Date:
08/04/2000
Publisher:
RSC
Main Group Chemistry / Edition 1

Main Group Chemistry / Edition 1

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Overview

Main Group Chemistry covers the chemistry of the s- and p-block elements, together with a brief chapter on the chemistry of zinc, cadmium and mercury, often classified as main group elements rather than as transition elements. The Periodic Table is an important predictive tool in main group chemistry and in this book, forms the basis for describing the trends and variations in the chemistry of the elements. Introductory material covers the basic principles behind the Periodic Table, bonding, electronegativity and VSEPR (Valence Shell Electron Pair Repulsion) theory. The chemistry of various groups of elements is then discussed. The book incorporates a valuable chapter on inorganic polymers, discussing the chemistry of materials such as silicates, silicones, phosphazenes and diamond. Additional material is available on the website at www.rsc.org/tct Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.


Product Details

ISBN-13: 9780854046171
Publisher: RSC
Publication date: 08/04/2000
Series: Tutorial Chemistry Texts , #3
Pages: 204
Product dimensions: 7.40(w) x 9.60(h) x 0.50(d)

About the Author

Professor Abel is an Emeritus Professor at the University of Exeter.

Read an Excerpt


Main Group Chemistry
by William Henderson, Eddie Abel

Preface

More than in any other region of the Periodic Table, the main group (sand p-block) elements are diverse, ranging from highly reactive nonmetallic elements such as fluorine, through semi-metals (e.g. silicon) to the highly reactive alkali metals. The Periodic Table itself is an excellent framework for the discussion of the trends in physical and chemical properties of the main group elements and their compounds. This book has been written with the aim of summarizing some of the more important features of the vast and varied chemistry of the main group elements, emphasizing some of the more important periodic trends and principles for rationalizing the properties. Discussion of the descriptive chemistry is backed up by worked examples and problems. Space restrictions have limited discussion of several areas where main group elements are significant players, such as bio-inorganic chemistry and industrial chemistry.

I would like to thank Professor Brian Nicholson, Dr. Richard Coll and Dr. Michael Taylor for many helpful comments on various drafts of the manuscript. I am also indebted to my wife, Angela, for giving me a teacher's point of view on the material.

Further problems, with answers, are available on the RSC's Tutorial Chemistry Texts website at http://www.chemsoc.org/tct/maingrouphome.htm

Bill Henderson
Hamilton, New Zealand

0471224804.txt |


Functional Group Chemistry
by James R. Hanson, Eddie Abel

Preface

The aim of this book is to provide anintroduction to the characteristic properties of functional groups. It is written for first-year undergraduates.

The book is in four chapters. The first is devoted to a general consideration of the bonding in functional groups, the classes of reagent and the types of reaction. Functional groups may be divided into several broad classes. The first of these are those functional groups in which the reactions, mainly substitution and elimination, are those of the s-bond. The chemistry of these functional groups forms the second chapter. A second class of functional groups is those in which a p-bond is a characteristic feature. The initial step in many of their reactions is an addition. These functional groups are described in the third chapter. The electrons within a p-bond may be symmetrically distributed as in an alkene, or unsymmetrically distributed as in the carbonyl group. The aromatic ring plays a major part in functional group chemistry. The final chapter is devoted to a description of the interaction between functional groups and the aromatic ring. Heteroaromatic compounds are considered in terms of the perturbation of the p-system brought about by the insertion of the heteroatom.

A balance has to be drawn in the use of systematic and trivial names. The IUPAC rules recognize that the use of trivial names for many simple compounds is often preferred. Students will meet these names in reading the current literature and on the bottles in the laboratory. However, because the systematic nomenclature forms the basis of documenting more complex structures, students need to be familiar with the use of systematic nomenclature by applying it to simple molecules. Both names will be given for compounds at appropriate stages in the text. An Appendix of Common and Systematic Names can be found on the RSC website (http://www.chemsoc.org/pdf/tct/functionalappendix.pdf), as well as a Further Reading list (http://www.chemsoc.org/pdf/tct/functionalreading.pdf).

I am indebted to Martyn Berry and Professor Sir John Cornforth AC FRS for their many valuable comments on the draft manuscript and particularly to Professor Alwyn Davies FRS for his substantial help and encouragement throughout the preparation of the manuscript and diagrams.

J. R. Hanson
Sussex

0471391832.txt |


CHAPTER 1

Introduction

The intention of this book is to give the accountant the answers to the largest possible number of accounting issues that are likely to arise. Thus, given the wide-ranging scope of this work, the reader should know about its overall structure in order to locate information more easily.

The Accounting Reference Desktop is divided into eight parts, each of which deals with a different aspect of the accounting function. The first part covers the role of accounting within the modern corporation. Chapter 2, The Role of Accounting, describes the primary tasks for which the accountant is responsible, as well as ethical concerns, and lists the job descriptions of the major positions to be found within the accounting department. Chapter 3, The Corporate Structure, describes the organizational layout of the typical corporation, how the transactional systems maintained by the accounting department interact with these other functions, and how the organizational structure can alter the types of accounting systems used.

The second part deals with accounting rules and regulations. Chapter 4, Standard Setting Organizations, describes the origins and responsibilities of the various rule-setting bodies that have created Generally Accepted Accounting Principles (GAAP), not only for United States business entities, but also for government and international organizations. Chapter 5, Accounting Standards, lists all of the various accounting pronouncements, such as FASB Interpretations, FASB Statements, and FASB Technical Bulletins, in summary form; the reader can peruse this list of original source documents in order to determine what additional research may be needed to delve into a particular GAAP issue. Chapter 6, The Securities and Exchange Commission, gives an overview of the Securities and Exchange Commission (SEC), the EDGAR online reporting system, and the Acts and SEC regulations that govern the reporting requirements of publicly held corporations.

The third part covers the general format and rules governing the information contained within accounting reports. Chapter 7, The Balance Sheet and Statement of Stockholders' Equity, describes the format of the balance sheet and statement of retained earnings, as well as the definitions of the various categories of assets, liabilities, and equity items that are listed in these reports. Chapter 8, The Income Statement, describes the format of the income statement, as well as the rules governing the presentation of information about discontinued operations, earnings per share, gains and losses, accounting changes, discontinued operations, extraordinary items, other comprehensive income, and prior period adjustments. Chapter 9, The Statement of Cash Flows, describes the format of the statement of cash flows, as well as exemptions from its use and how to handle foreign currency translations when constructing it. Chapter 10, Footnotes, describes a broad range of disclosures that an accountant may be required to attach to the financial statements in the form of footnotes. Chapter 11, Internal Management Reports, departs from the previous chapters in this part, in that it describes reports that are entirely "free form," designed entirely for internal use and not prescribed in format by any accounting pronouncement. These include status, margin, cash, capacity, sales and expense, and payroll reports. The part concludes with Chapter 12, Foreign Currency Translation, which covers the proper treatment of foreign currency translation, including the use of the current rate translation method and the remeasurement method, as well as the proper accounting for foreign exchange sale transactions and the recognition of translation adjustments.

The fourth part departs from the reporting format of the financial statement and delves into the accounting rules and transactions for each of the asset, liability, equity, and revenue categories. Chapter 13, Cash and Investments, defines cash and investments, describes the different types of marketable securities, derivatives, and long-term investments, and how each one is accounted for. Chapter 14, Inventory, describes the types of inventory, how to install an inventory tracking system, the physical inventory counting procedure, and the use of the LIFO, FIFO, average, retail, dollar-value LIFO, and gross margin methods for valuing inventory. The chapter also describes the lower of cost or market rule and the process to follow when allocating overhead costs to inventory. Chapter 15, Accounts Receivable, describes the accounts receivable transaction flow, as well as how to account for factored accounts receivable, sales returns, early payment discounts, long-term accounts receivable, and bad debts. Chapter 16, Fixed Assets, describes the use of a capitalization limit when accounting for newly acquired fixed assets, as well as the proper accounting for newly acquired assets, improvements to existing assets, the disposition of assets, construction in progress, and leasehold improvements. It also covers the various types of depreciation that may be used to account for the gradual reduction in value of fixed assets.

Chapter 17, Current Liabilities, describes the accounts payable transaction flow, and how to account for the period-end cut-off of accounts payable transactions. It also covers the proper accounting for advance payments from customers, accrued expenses, unclaimed wages, interest payable, dividends, termination benefits, estimated product returns, and contingent liabilities. Chapter 18, Debt, describes basic bond transactions and accounting for a bond discount or premium, as well as for non-interest bearing notes payable. It also covers non-cash debt payments, early debt retirement, callable debt, defaulted debt, warrants, sinking funds, bonds converted to equity, and short-term debt that is being refinanced. Chapter 19, Equity, covers the transactions related to common stock, as well as stock options, stock appreciation rights, stock warrants, dividends, stock subscriptions, stock splits, stock retirement, and employee stock ownership plans. Chapter 20, Revenue, covers the multitude of revenue recognition rules, including variations under the accrual method, cash method, installment sales method, completed contract method, percentage of completion method, proportional performance method, production method, and deposit method. It also discusses the special rules related to bill and hold transactions, brokered transactions, appreciation, and initiation fees. Chapter 21, Research and Development, describes the proper accounting for in-house R&D costs, as well as for acquired R&D costs, R&D costs contracted to another party, and the special case of R&D costs in the software industry.

The fifth part of the book covers the crucial area of accounting management. This is the core function for many accountants, who can provide value to the organization through the use of better control systems, financial analysis of key investments, and higher levels of departmental efficiency. Chapter 22, Best Practices, covers several dozen of the most common best practices that can improve a company's performance, including the areas of accounts payable, collections, commissions, filing, finance, financial statements, the general ledger, invoicing, inventory, management, and payroll. For a thorough treatment of this topic, the reader can also consult the author's Accounting Best Practices, 2nd Edition (John Wiley & Sons, 2001). Chapter 23, Budgeting, explains the system of interlocking departmental budgets, and presents a sample budget. It also covers a number of budgeting best practices and control systems that assist the accountant in creating a budget in the most efficient manner possible. Chapter 24, Closing the Books, focuses on the various steps required to achieve a fast close, and also describes the steps needed to achieve an instantaneous close. Chapter 25, Control Systems, presents a list of the most essential control points that the accountant should be concerned with. It also discusses the times when it may be appropriate to eliminate controls for efficiency reasons, and covers the various types of fraud that some of these controls are designed to detect and mitigate. Chapter 26, Cost Accounting, focuses on the many types of advanced data collection systems that can be used to compile data for use by cost accounting systems. It also describes the major costing systems that can be used to interpret this data, such as job costing, process costing, standard costing, direct costing, and activity-based costing. It also covers the concepts of throughput accounting, target costing, by-product costing, and cost variances. These topics are covered in more detail in the author's Cost Accounting (John Wiley & Sons, 2001). Chapter 27, Financial Analysis, describes how to calculate a company's cost of capital, analyze a capital purchasing decision, discount future cash flows, and conduct both breakeven and risk analyses. These topics and more are described in additional detail in the author's Financial Analysis (John Wiley & Sons, 2000). Chapter 28, Management Information Systems, covers information system strategy, how to evaluate and select packaged accounting software, and how to install and test it. The chapter also addresses information system security, data collection and storage tools, electronic data interchange, outsourcing all or portions of the function, and the integration of the accounting system with other computer systems located elsewhere in a company. Finally, Chapter 29, Records Management, deals with the cost of various types of record keeping systems, the policies and procedures required for proper record storage, and the types of tax records that must be kept on hand.

The sixth part of the book deals with financial management, which includes customer credit, cash management, long-term financing, and risk management--all topics that are of particular interest to accountants in smaller organizations that do not have separate finance departments. Chapter 30, Customer Credit, describes the types of selling terms that can be extended, how to conduct a credit investigation, and various techniques for collecting overdue accounts receivable. Chapter 31, Financing, describes how to minimize a company's financing needs through proper management, how to deal with banks, and the pros and cons of delaying payments to suppliers. It also addresses the use of factoring and field warehouse financing, floor planning, inventory reduction, leasing, lines of credit, asset-based loans, bonds, bridge loans, preferred stock, sale and leaseback arrangements, and various types of debt in order to deal with a company's financing requirements. Chapter 32, Cash Management, describes the use of a cash forecasting model and its automation, as well as how to more tightly control cash outflows and how to invest short-term funds. Chapter 33, Risk Management, describes the risk management policies and procedures that can be used to determine and mitigate risks, as well as the types of insurance that are available to reduce any remaining risks. It also describes the claims administration process, claims documentation, and the format of the annual risk management report.

The seventh part of the book deals with two major topics that do not fit easily into any of the preceding categories--mergers and acquisitions, and taxation. In Chapter 34, Mergers and Acquisitions, we cover the accounting required to record a business combination under both the purchase and pooling methods of accounting. The chapter also describes how to record investments in a subsidiary by using the cost method, equity method, or consolidation method. It also delves into inter-company transactions in relation to consolidated financial reporting, contingent payments for a business combination, push-down accounting, leveraged buyouts, spin-off transactions, and the proper treatment of goodwill. Chapter 35, Taxation, covers nearly 50 taxation issues, including the Alternative Minimum Tax, partnership taxation, deferred compensation, stock options, and transfer pricing.

The final part of the Accounting Reference Desktop is the appendices, which include additional reference information that the accountant is likely to require on a regular basis. Appendix A describes the different types of account code structures that can be used in a chart of accounts, and gives sample charts of accounts for each structure. Appendix B contains a list of the most common journal entries that an accountant is likely to deal with. Appendix C contains interest rate tables, as well as the formulas used to derive them. These tables cover simple interest, compound interest, the present value of an annuity, and the future amount of an annuity. Appendix D contains more than 40 ratios that can be used to determine a company's financial condition. Finally, Appendix E contains a dictionary of the many accounting terms that are addressed in this book.

In short, the Accounting Reference Desktop is a complete source of information for the practicing accountant. By using the table of contents, this introduction, and the index to locate information, one can find the answers to most everyday accounting questions in this book.

Table of Contents

Some Aspects of Structure and Bonding in Main Group Chemistry;
The Chemistry of Hydrogen;
The Group 1 (Alkali Metal) Elements: Lithium, Sodium, Potassium, Rubidium, Caesium and Francium;
The Group 2 Elements: Beryllium, Magnesium, Calcium, Strontium, Barium and Radium;
The Group 13 Elements: Boron, Aluminium, Gallium, Indium and Thallium;
The Group 14 Elements: Carbon, Silicon, Germanium, Tin and Lead;
The Group 15 (Pnictogen) Elements: Nitrogen, Phosphorus, Arsenic, Antimony and Bismuth;
The Group 16 (Chalcogen) Elements: Oxygen, Sulfur, Selenium, Tellurium and Polonium;
The Group 17 (Halogen) Elements: Fluorine, Chlorine, Bromine, Iodine and Astatine;
The Group 18 (Noble Gas) Elements: Helium, Neon, Argon, Krypton, Xenon and Radon;
The Group 12 Elements: Zinc, Cadmium and Mercury;
Selected Polymeric Main Group Compounds;
Subject Index.

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