The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials / Edition 1

by Knut Rurack, Ramon Martinez-Manez

Overview

The combination of supramolecular chemistry, inorganic solids, and nanotechnology has already led to significant advances in many areas such as sensing, controlled motion, and delivery. By making possible an unprecedented tunability of the properties of nanomaterials, these techniques open up whole new areas of application for future supramolecular concepts. The Supramolecular Chemistry of Organic–Inorganic Hybrid Materials gathers current knowledge on the subject and provides an overview of the present state and upcoming challenges in this rapidly growing, highly cross- or interdisciplinary research field.

The book details how these designed materials can improve existing materials or generate novel functional features such as chemical amplification, cooperative binding and signal enhancement that are difficult or not at all achievable by classical organic supramolecular chemistry. It also discusses issues related to nanofabrication or nanotechnology such as the directed and controlled assembly or disassembly, biomimetic functions and strategies, and the gating and switching of surface functions or morphology.

 

Product Details

ISBN-13:	9780470376218
Publisher:	Wiley
Publication date:	03/22/2010
Pages:	800
Product dimensions:	6.50(w) x 9.30(h) x 1.80(d)

About the Author

KNUT RURACK received his PhD from Humboldt University of Berlin and then joined the BAM Federal Institute for Materials Research and Testing where he currently leads a group in the Bioanalytics Division. The coauthor of over 70 research publications and one patent, he is a member of the German and American Chemical Societies.

RAMÓN MARTÍNEZ-MÁÑEZ received his PhD in chemistry from the University of Valencia and was a postdoctoral fellow at Cambridge University, UK. He is currently a full professor in the Department of Chemistry at the Polytechnic University of Valencia and the coauthor of more than 170 research publications and eight patents. He is a member of the American Chemical Society.

Table of Contents

Preface ix

Editors and Contributors xiii

Abbreviations xix

1 Hybrid (Nano)Materials Meet Supramolecular Chemistry: A Brief Introduction to Basic Terms and Concepts Knut Rurack Ramón Martínez-Máñez 1

2 Supramolecular Chemistry at the Mesoscale Katsuhiko Ariga Gary J. Richards Jonathan P. Hill Ajayan Vinu Toshiyuki Mori 11

Part 1 Organic-Inorganic Hybrid Nanomaterials

3 Silica-Based Mesoporous Organic-Inorganic Hybrid Material Frank Hoffmann Michael Fröba 39

4 Modified Gold Nanoparticles and Surfaces Paolo Pengo Lucia Pasquato 113

5 Organically Functionalized Semiconductor Nanocrystals: Synthesis, Properties and System Design for Optoelectronic Applications Peter Reiss Julia de Girolamo Adam Pron 155

6 Functionalized Carbon Nanotubes for Bioapplications Lingrong Gu Fushen Lu Pengju G. Luo Haifang Wang Mohammed J. Meziani Ya-Ping Sun 197

7 Metal-Organic Frameworks (MOFs) and Coordination Polymers Shin-Ichiro Noro Susumu Kitagawa 235

Part 2 Improvement-of Signaling and Sensing by Organization on Surfaces

8 Nanoparticle and Biomolecular-Nanoparticle Hybrid Supramolecular Complexes for Electrochemical Signaling Ronen Polsky Jason C. Harper Susan M. Brozik 273

9 Modified Nanoparticles as Nanoelectrocatalysts and Amplifying Sensors Shaojun Guo Erkang Wang Xiurong Yang 297

10 Signal Generation with Gold Nanoparticles: Photophyskal Properties for Sensor and Imaging Applications Qingshan Wei Alexander Wei 319

11 Optical Signaling with Silica Nanoparticles Fabrizio Mancin Paolo Tecilla Umberto Tonellato 351

12 Organically Modified Quantum Dots in Chemical and Biochemical Analysis María Teresa Fernández Argüelles José M. Costa-Fernández Rosario Pereiro Alfredo Sanz-Medel 377

Part 3 Control of Supramolecular Nanofabrication, Motion, and Morphology

13 Chemically Directed Self-Assembly of Nanoparticle Structures on Surfaces Xing Yi Ling David N. Reinhoudt Jurriaan Huskens 407

14 Immobilization and Patterning of Biomolecules on Surfaces Dorota I. Rozkiewicz Ban Jan Ravoo David N. Reinhoudt 433

15 Switchable Host-Guest Chemistry on Surfaces Jilie Kong Chunming Jiang Li Mu 467

16 Nanogated Mesoporous Silica Materials Igor I. Slowing Brian G. Trewyn Victor S.-Y. Lin 479

17 Building Molecular Machines on Surfaces Alberto Credi Serena Silvi Margherita Venturi 503

18 Control of Morphology in Mesoporous and Mesostructured Hybrid Materials Darren R. Dunphy Bernd Smarsly C. Jeffrey Brinker 531

Part 4 Biomimetic Chemistry

19 Biomimetically Inspired Signaling Knut Rurack Ramón Martínez-Máñez Fléix Sancenón Ana B. Descalzo 549

20 Imprinted Functionalized Silica Maryanne M. Collinson 581

21 Bioinspired Block Copolymer-Based Hybrid Materials Marleen Kamperman Ulrich Wiesner 599

Part 5 Interfacial Chemistry, Multifunctionality, and Interdisciplinarity

22 Emerging Concepts in Interfacial Chemistry of Hybrid Materials: Nanocontainer-Based Self-Healing Coatings Dmitry G. Shchukin Daria V. Andreeva Katja Skorb Helmuth Möhwald 639

23 Molecular Schizophrenics: Switchable Materials with Multiple Functions Robert Byrne Dermot Diamond 653

24 Hybrid Nanomaterials Research: Is It Really Interdisciplinary? Ismael Rafols Martin Meyer Jae-Hwan Park 673

25 Supramolecular Chemistry Meets Hybrid (Nano)Materials: A Brief Look Ahead Knut Rurack Ramón Martínez-Máñez 689

Appendix 1 701

Index 707

What People are Saying About This

From the Publisher

"This book will find use for those generally interested in such hybrid systems. With some prior knowledge, one can browse through the topics and then proceed to the literature for more complete and in-depth coverage." (JACS, 2010)

Editorial Reviews

"This book will find use for those generally interested in such hybrid systems. With some prior knowledge, one can browse through the topics and then proceed to the literature for more complete and in-depth coverage." (JACS, 2010)

From the Publisher