Synthesis of Methylated Bucky Bowls by HF elimination
Wissenschaftlicher Aufsatz aus dem Jahr 2015 im Fachbereich Chemie - Organische Chemie, , Sprache: Deutsch, Abstract: Here a short route towards the synthesis of a methylated bucky-ball is reported according to previous stated synthesis. The synthesis comprises a sequence of a Wittig-Horner reaction, followed by a photocyclization. Bromination provides the starting material for a second Wittig-Horner reaction with following photocyclization. The key step of the syn-thesis is the cove-region closure process (CRC) facilitated by regiospecific HF elimination, promoted through activated aluminium oxide. The final product exhibits the characteristic bowl-like shape. Different reaction conditions were applied for the key step in order to increase the yield and minimize the amount of side products.
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Synthesis of Methylated Bucky Bowls by HF elimination
Wissenschaftlicher Aufsatz aus dem Jahr 2015 im Fachbereich Chemie - Organische Chemie, , Sprache: Deutsch, Abstract: Here a short route towards the synthesis of a methylated bucky-ball is reported according to previous stated synthesis. The synthesis comprises a sequence of a Wittig-Horner reaction, followed by a photocyclization. Bromination provides the starting material for a second Wittig-Horner reaction with following photocyclization. The key step of the syn-thesis is the cove-region closure process (CRC) facilitated by regiospecific HF elimination, promoted through activated aluminium oxide. The final product exhibits the characteristic bowl-like shape. Different reaction conditions were applied for the key step in order to increase the yield and minimize the amount of side products.
17.92
In Stock
5
1
Synthesis of Methylated Bucky Bowls by HF elimination
14
Synthesis of Methylated Bucky Bowls by HF elimination
14
17.92
In Stock
Product Details
| ISBN-13: | 9783668255616 |
|---|---|
| Publisher: | GRIN Verlag GmbH |
| Publication date: | 01/01/2016 |
| Sold by: | CIANDO |
| Format: | eBook |
| Pages: | 14 |
| File size: | 433 KB |
| Language: | German |
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