Disc 1
- I'll Be Around - Spinners
- Tell It Like It Is - Aaron Neville
- Rainy Night in Georgia - Brook Benton
- Try a Little Tenderness - Otis Redding
- I Found a Love - Wilson Pickett
- When a Man Loves a Woman - Percy Sledge
- Angel - Aretha Franklin
- Patches - Clarence Carter
- Thin Line Between Love and Hate - Persuaders
- Love Makes the World Go 'Round - Deon Jackson
- I've Been Loving You Too Long (To Stop Now) - Jerry Butler - Otis Redding
- Baby, I'm Yours - Barbara Lewis - Van McCoy
- Cry to Me - Betty Harris
- Tonight's the Night - Solomon Burke - Don Covay
- Just One Look - Doris Troy
- Stay with Me - Lorraine Ellison - Jerry Ragovoy
Disc 2
- One of a Kind (Love Affair) - Spinners
- (You Make Me Feel Like) A Natural Woman - Aretha Franklin - Gerry Goffin - Carole King - Jerry Wexler
- I'm in Love - Wilson Pickett - Bobby Womack
- (If Loving You Is Wrong) I Don't Want to Be Right - Homer Banks - Luther Ingram
- Slip Away - Clarence Carter
- Walk on By - Burt Bacharach - Hal David - Dionne Warwick
- Natural High - Bloodstone
- Love on a Two-Way Street - Moments
- Make Me Your Baby - Barbara Lewis
- Release Me - Esther Phillips
- Hypnotized - Linda Jones
- That's the Way I Feel About 'Cha - Bobby Womack
- If You Need Me - Solomon Burke - Wilson Pickett
- B-A-B-Y - Isaac Hayes - David Porter - Carla Thomas
- Pain in My Heart - Otis Redding
- When Something Is Wrong with My Baby - Isaac Hayes - David Porter - Sam & Dave
Disc 3
- Never Can Say Goodbye - Jackson 5
- Baby I Need Your Loving - Lamont Dozier - Four Tops - Brian Holland - Eddie Holland
- My Cherie Amour - Henry Cosby - Sylvia Moy - Stevie Wonder
- Just My Imagination (Running Away with Me) - Barrett Strong - Temptations - Norman Whitfield
- Ain't Nothing Like the Real Thing - Nickolas Ashford - Marvin Gaye - Valerie Simpson - Tammi Terrell
- Stop! In the Name of Love - Lamont Dozier - Brian Holland - Eddie Holland - Supremes
- Ooo Baby Baby - Miracles - Smokey Robinson
- It's a Man's Man's Man's World - James Brown
- Funny (How Time Slips Away) - Joe Hinton
- Cry Baby - Mimms
- Turn Back the Hands of Time - Tyrone Davis
- Sitting in the Park - Billy Stewart
- Woman's Gotta Have It - Bobby Womack
- What Kind of Fool (Do You Think I Am) - Tams
- Searching for My Love - Moore
- I Had a Talk with My Man Last Night - Mitty Collier
Disc 4
- Too Busy Thinking About My Baby - Marvin Gaye - Barrett Strong - Norman Whitfield
- I'm Still in Love with You - Al Green - Al Jr. Jackson - Willie Mitchell
- Oh Girl - Chi-Lites - Eugene Record
- My Guy - Smokey Robinson - Mary Wells
- Crying Time - Ray Charles
- There'll Come a Time - Betty Everett - Eugene Record
- Oh, What a Night - Dells
- Woman to Woman - Shirley Brown
- Baby, I'm for Real - Marvin Gaye - Originals
- What Becomes of the Brokenhearted - Jimmy Ruffin
- You Make Me Feel Brand New - Stylistics
- Hey There Lonely Girl - Eddie Holman
- Baby, Baby Don't Cry - Smokey Robinson - Robinson
- Since I Lost My Baby - Smokey Robinson - Temptations
- Mama Didn't Lie - Jan Bradley - Curtis Mayfield
- Every Little Bit Hurts - Brenda Holloway
Disc 5
- How Sweet It Is (To Be Loved by You) - Lamont Dozier - Marvin Gaye - Brian Holland - Eddie Holland
- I'll Be There - Willie Hutch - Jackson 5
- The Tracks of My Tears - Miracles - Smokey Robinson
- Stay in My Corner - Dells - Barrett Strong
- The Thrill Is Gone - B.B. King
- Our Day Will Come - Ruby & the Romantics
- Two Lovers - Smokey Robinson - Mary Wells
- I'm So Proud - Impressions - Curtis Mayfield
- My Girl - Smokey Robinson - Temptations
- You're All I Need to Get By - Nickolas Ashford - Marvin Gaye - Valerie Simpson - Tammi Terrell
- Betcha by Golly, Wow - Stylistics - Russell Jr. Thompkins
- Love Is a Hurtin' Thing - B. Raleigh - Lou Rawls
- Never Give You Up - Jerry Butler - Kenny Gamble - Leon Huff
- My Whole World Ended (The Moment You Left Me) - David Ruffin
- What Does It Take (To Win Your Love) - Walker
- Jealous Kind of Fella - Garland Green
Disc 6
- Someday We'll Be Together - Ross
- You Really Got a Hold on Me - Miracles - Smokey Robinson
- Let's Get It On - Marvin Gaye
- Sunny - Bobby Hebb
- I Wish It Would Rain - Barrett Strong - Temptations - Norman Whitfield
- If I Were Your Woman - Knight
- Have You Seen Her - Chi-Lites - Eugene Record
- Love Makes a Woman - Barbara Acklin - Eugene Record
- In the Rain - Dramatics
- The Bells - Marvin Gaye - Originals
- Let's Go Get Stoned - Nickolas Ashford - Ray Charles - Valerie Simpson
- I'll Be Doggone - Marvin Gaye - Smokey Robinson
- That's the Way Love Is - Bobby "Blue" Bland
- I Do Love You - Billy Stewart
- Nothing Takes the Place of You - Toussaint McCall
- Rainbow '65, Pt. 1 - Gene Chandler - Curtis Mayfield
Disc 7
- Ain't No Sunshine - Bill Withers
- Midnight Train to Georgia - Knight
- Me and Mrs. Jones - Kenny Gamble - Leon Huff - Billy Paul
- If You Don't Know Me by Now - Kenny Gamble - Leon Huff - Melvin
- Everybody Plays the Fool - Main Ingredient
- Hurt So Bad - Little Anthony & the Imperials
- Close Your Eyes - Peaches & Herb
- The Chokin' Kind - Joe Simon
- La-La Means I Love You - Delfonics
- Cowboys to Girls - Kenny Gamble - Leon Huff - Intruders
- Mercy, Mercy, Mercy - Cannonball Adderley - Joe Zawinul
- Yes, I'm Ready - Barbara Mason
- Oh No, Not My Baby - Maxine Brown - Gerry Goffin - Carole King
- Dry Your Eyes - Brenda & the Tabulations
- The Love of My Man - Theola Kilgore
Disc 8
- Let's Stay Together - Al Green - Al Jr. Jackson - Willie Mitchell
- Best Thing That Ever Happened to Me - Knight
- Didn't I (Blow Your Mind This Time) - Delfonics
- The Love I Lost - Kenny Gamble - Leon Huff - Melvin
- Going in Circles - Friends of Distinction
- Little Green Apples - O.C. Smith
- Lean on Me - Bill Withers
- Um, Um, Um, Um, Um, Um - Major Lance - Curtis Mayfield
- The Dark End of the Street - James Carr
- Piece of My Heart - Bert Berns - Erma Franklin - Jerry Ragavoy
- You'll Lose a Good Thing - Barbara Lynn
- I'm Your Puppet - Bobby Purify - James Purify
- Hold What You've Got - Joe Tex
- Are You Lonely for Me Baby - Bert Berns - Freddie Scott
Disc 9
- Groove Me - King Floyd
- I'll Take You There - Staple Singers
- Mr. Big Stuff - Jean Knight
- Who's Making Love - Homer Banks - Johnnie Taylor
- We're Gonna Make It - Little Milton
- Don't Let the Green Grass Fool You - Wilson Pickett
- Rescue Me - Fontella Bass
- Tired of Being Alone - Al Green
- It Hurts So Good - Millie Jackson
- Ain't Nothing You Can Do - Bobby "Blue" Bland
- Got to Get You Off My Mind - Solomon Burke
- Starting All Over Again - Mel & Tim
- Baby Scratch My Back - Slim Harpo
Disc 10
- I Got You (I Feel Good) - James Brown
- I Heard It Through the Grapevine - Knight - Barrett Strong - Norman Whitfield
- Respect Yourself - Staple Singers
- Clean Up Woman - Willie Clarke - Clarence Reid - Betty Wright
- Power of Love - Kenny Gamble - Leon Huff - Joe Simon
- Part-Time Love - Little Johnny Taylor
- Tell Mama - Etta James
- Don't Play That Song (You Lied) - Ahmet Ertegun - Aretha Franklin
- Can I Change My Mind - Tyrone Davis
- Wang Dang Doodle - Willie Dixon - Koko Taylor
- I Want To (Do Everything for You) - Joe Tex
- Lookin' for a Love - Bobby Womack