Table of Contents
Preface ix
Alkanes 1
Isomers 5
Cycloalkanes 7
Heteranes 9
Nomenclature of Alkyl Groups 10
Traditional Names 10
Cycloalkyl Groups 18
Nomenclature of Alkanyl Groups 19
Preferred Names 20
Alkenes 22
Substituent Groups Related to Alkenes 25
Stereoisomers (Spatial Isomers) 27
Dienes 32
Bivalent Groups 33
Alkynes 35
Alkynyl Groups 36
Multiple Multiple Bonds 36
Aromatic Hydrocarbons (Arenes) 38
Substitution Products from Aromatic Hydrocarbons 46
Radicals and Ions 50
Radicals 50
Methylenes, Alkylidenes 51
Carbocations and Carbanions 52
Alcohols and Phenols 55
Substitutive, Preferred Names for Alcohols 55
Alcohols with Two or More Characteristic Groups 58
OH as Substitutent 59
Functional Class Names of Alcohols 60
Phenols 61
Ethers 63
Substitutive, Preferred Names 63
Functional Class Names 65
Polyethers and Replacement Nomenclature 65
Acids 67
Carboxylic Acids 67
Preferred Names-Acyclic Carboxylic Acids 67
Preferred Names-Cyclic Carboxylic Acids 70
Retained Names for Arenecarboxylic Acids 71
Peroxy Acids 72
Sulfonic Acids 73
Acid Derivatives 75
Acid Anhydrides 75
Acyl Halides 77
Salts 78
Esters 79
Amides 82
Acid-related Groups as Substituents 83
Nitriles 85
Aldehydes 87
Aldehyde Groups as Substituents 90
Ketones 91
Cyclic Pseudoketones 93
Carbonyl Group as Substituent 94
Amines, Imines, and Related Cations 95
Amines 95
Cations from Amines 99
Imines 100
Bridged Ring Systems 102
Appendix 109
Selected References 109
A Brief Summary of Some Key IUPAC Rules for Preferred Substitutive Names of Organic Compounds 110
Substitutive Name Prefixes and Suffixes for Some Important Characteristic Groups 111
Preferred Names of Some Cyclic Parent Compounds Included in This Program 112
Replacement Name Prefixes for Some Heteroatoms 112
Some Numerical Terms Used in Chemical Names 113
Answer Sheets 114
