Melt Crystallization Technology

From the Author's Preface: There is a growing demand for ultrapure organic compounds such as fine chemicals, pharmaceuticals, and basic materials for use in the polymer industry. . . . In quite a number of cases, it is difficult or impossible to manufacture ultrapure organics efficiently using conventional separation techniques such as distillation. Moreover, conventional techniques usually require large amounts of energy. To improve the purification efficiency of organics, special techniques based on crystallization from the melt have been developed. Melt crystallization meets industry's need for a highly selective separation process for organic compounds which operates at low enough temperatures to prevent thermal degradation. Melt crystallization processes have the added advantage that they are energy-efficient and ecologically sound. Melt crystallization techniques appear to be particularly promising for upgrading organic materials and are one of the few routes that appear to be feasible for purifying starter materials for high-tech polymers. The aim of this book is to provide basic information on melt crystallization technology. . . . This monograph consists of three parts: 1. basic principles, 2. process options, and 3. technical equipment and applicability. This new book is the first unified guide and reference to an important chemical process technology. It is comprehensive and organized for easy reference. More than 150 diagrammatic representations, flow charts and photographs illustrate equipment and processes. More than 40 tables provide useful reference data.

"1127473142"
Melt Crystallization Technology

From the Author's Preface: There is a growing demand for ultrapure organic compounds such as fine chemicals, pharmaceuticals, and basic materials for use in the polymer industry. . . . In quite a number of cases, it is difficult or impossible to manufacture ultrapure organics efficiently using conventional separation techniques such as distillation. Moreover, conventional techniques usually require large amounts of energy. To improve the purification efficiency of organics, special techniques based on crystallization from the melt have been developed. Melt crystallization meets industry's need for a highly selective separation process for organic compounds which operates at low enough temperatures to prevent thermal degradation. Melt crystallization processes have the added advantage that they are energy-efficient and ecologically sound. Melt crystallization techniques appear to be particularly promising for upgrading organic materials and are one of the few routes that appear to be feasible for purifying starter materials for high-tech polymers. The aim of this book is to provide basic information on melt crystallization technology. . . . This monograph consists of three parts: 1. basic principles, 2. process options, and 3. technical equipment and applicability. This new book is the first unified guide and reference to an important chemical process technology. It is comprehensive and organized for easy reference. More than 150 diagrammatic representations, flow charts and photographs illustrate equipment and processes. More than 40 tables provide useful reference data.

262.99 In Stock
Melt Crystallization Technology

Melt Crystallization Technology

by Tine Arkenbout-de Vroome
Melt Crystallization Technology

Melt Crystallization Technology

by Tine Arkenbout-de Vroome

eBook

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Overview

From the Author's Preface: There is a growing demand for ultrapure organic compounds such as fine chemicals, pharmaceuticals, and basic materials for use in the polymer industry. . . . In quite a number of cases, it is difficult or impossible to manufacture ultrapure organics efficiently using conventional separation techniques such as distillation. Moreover, conventional techniques usually require large amounts of energy. To improve the purification efficiency of organics, special techniques based on crystallization from the melt have been developed. Melt crystallization meets industry's need for a highly selective separation process for organic compounds which operates at low enough temperatures to prevent thermal degradation. Melt crystallization processes have the added advantage that they are energy-efficient and ecologically sound. Melt crystallization techniques appear to be particularly promising for upgrading organic materials and are one of the few routes that appear to be feasible for purifying starter materials for high-tech polymers. The aim of this book is to provide basic information on melt crystallization technology. . . . This monograph consists of three parts: 1. basic principles, 2. process options, and 3. technical equipment and applicability. This new book is the first unified guide and reference to an important chemical process technology. It is comprehensive and organized for easy reference. More than 150 diagrammatic representations, flow charts and photographs illustrate equipment and processes. More than 40 tables provide useful reference data.


Product Details

ISBN-13: 9781351432221
Publisher: CRC Press
Publication date: 01/31/2021
Sold by: Barnes & Noble
Format: eBook
Pages: 383
File size: 36 MB
Note: This product may take a few minutes to download.

About the Author

Tine Arkenbout-de Vroome. Dr. Arkenbout studied chemistry at the University of Utrecht, and joined TNO, the Netherlands Organization for Applied Scientific Research. He has specialized in research on new separation processes and has had thirty of his articles on this subject published.

Table of Contents

I. Basic Principles 1. Prospects of Melt Crystallization General Introduction The Method of Melt Crystallization Energy Efficiency, Environmental Impact Process Options Some Alternative Techniques 2. Basic Principles in Crystallization Introduction Crystal Structure, Morphology Crystal Growth, Mechanisms 3. Thermodynamic Limits Solid-Liquid Equilibria Product Purity Recovery Prediction of Eutectic Compositions Prediction of Miscibility in the Solid Phase Methods to Improve Recovery Conclusions 4. Kinetic Limits Incorporation of Impurities into Crystals Effective and Integral Distribution Coefficient Purification Efficiency in Dependence on Process Conditions Purity Attainable by One Single Crystallization Operation 5. Further Purification Scope of Techniques Washing Sweating Recrystallization II. Process Options 6. Layer Growth Normal Freezing Operation Principle Multistage Operation Continuous Layer Growth 7. Suspension Growth Growth, Kinetics Proper Crystal Size Agglomeration, Breakage Approach to Technical Crystallizer Crystallizer Configuration Crystallizer Cascades 8. Crystal-Melt Separation The Washing Operation Countercurrent Separation Columns Based on Gravity Transport The Kureha Continuous Crystal Purifier Wash-Columns Based on Forced Transport Two-Stage Crystal-Melt Separation Comparison between the Two Types of Wash-Columns 9. On the Choice of the Process Option Crystal Layer Processes Suspension Growth Processes Flow Diagrams for Suspension Growth Comparison between Layer and Suspension Growth 10. Melt Crystallization Feasibility Applicability Collection of Physical Data Orientating Tests Laboratory-Scale Experiments Pilot Plant Tests Technological Study III. Technical Equipment, Applicability 11. Technical Equipment for Crystal Layer Growth Survey of Commercially Available Equipment Commercial Static Layer Growth Processes Commercial Dynamic Layer Growth Processes 12. Technical Equipment for Suspension Growth Survey of Commercially Available Equipment Installations with Gravity Transport Columns Installations with Forced Transport Columns 13. Technical Applicability Scope of Technique Para-Xylene Acetic Acid Acrylic Acid Cyclohexane para-Dichlorobenzene Maleic Anhydride Phenol Caprolactam Naphthalene para-Chloronitrobenzene 4,4-Diphenylmethanediisocyanate (MDI) Survey of Technical Applications 14. Technical Implementation of Melt Crystallization Introduction Increase of Product Purity Increase of Recovery Replacement of Solution Crystallization by Melt Crystallization Recovery of Solvents 15. Related Fields of Application Introduction Freeze Concentration Dry Fractionation of Fats and Fatty Acids Dewaxing of Oils Use of Wash-Columns Outside Melt Crystallization 16. Status of Development, Future Outlook

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