| Armie Hammer | Illya Kuryakin |
| Henry Cavill | Napoleon Solo |
| Elizabeth Debicki | Victoria Vinciguerra |
| Alicia Vikander | Gaby Teller |
| Hugh Grant | Waverly |
| Jared Harris | Sanders |
| Luca Calvani | Alexander |
| Sylvester Groth | Uncle Rudi |
| Christian Berkel | Udo |
| Misha Kuznetsov | Oleg |
| Guy Williams | Captain Smith |
| Marianna DiMartino | Desk Clerk |
| Julian Michael Deuster | Assistant |
| Andrea Cagliesi | Fishing Captain |
| Riccardo Calvanese | Man 2 |
| Peter Stark | Guard |
| David Menkin | Jones |
| Pablo Scola | Harbourmaster |
| Cesare Taurasi | Mechanic |
| Riccardo Flammini | Man 1 |
| Francesco De Vito | Night Manager |
| Luca DellaValle | Security Guard |
| Simona Caparrini | Contessa |
| David Beckham | Projectionist |
| Alessandro Ananasso | Italian Guard |
| Joana Metrass | Victoria's Assistant |
| Gabriel Farnese | Italian Playboy 1 |
| Elbio Bonsaglio | Italian Playboy 2 |
| Michael Peluso | Italian Playboy 3 |
| Alan Turkington | Lead Policeman |
| Sergio Marini | Guard |
Technical Credits
| Guy Ritchie | Director,Producer,Screenwriter |
| David Allday | Art Director |
| Guy Bradley | Art Director |
| Toby Britton | Art Director |
| Steve Clark-Hall | Producer |
| John Davis | Producer |
| David Dobkin | Executive Producer |
| Peter Eskelsen | Associate Producer |
| Kate Grimble | Art Director |
| James Herbert | Editor |
| Paul Jennings | Stunts |
| Joanna Johnston | Costumes/Costume Designer |
| Max Keene | Asst. Director,Co-producer |
| Jeff Kleeman | Original Story |
| John Mathieson | Cinematographer |
| Steven Mnuchin | Executive Producer |
| Sarah Monzani | Makeup |
| Mark Mostyn | Co-producer |
| Daniel Pemberton | Score Composer |
| Reg Poerscout-Edgerton | Casting |
| Oliver Scholl | Production Designer |
| Remo Tozzi | Art Director |
| Lionel Wigram | Producer,Screenwriter |
| David C. Wilson | Original Story |