Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry: International Series in Organic Chemistry

by L. M. Jackman, S. Sternhell, D. H. R. Barton (Editor), W. Doering (Editor)

Overview

Applications of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, Second Edition focuses on the applications of nuclear magnetic resonance spectroscopy to problems in organic chemistry and the theories involved in this kind of spectroscopy. The book first discusses the theory of nuclear magnetic resonance, including dynamic and magnetic properties of atomic nuclei, nuclear resonance, and relaxation process. The manuscript also examines the experimental method. Topics include experimental factors that influence resolution and the shapes of absorption lines; measurement of line positions and identification of the chemical shift; and measurement of intensities. The text reviews the theories of chemical effects in nuclear magnetic resonance spectroscopy and spin-spin multiplicity and the theory and applications of multiple irradiation. The book also tackles the theory of chemical shift, including the classification of shielding effects, local diamagnetic proton shielding, solvent effects, and contact shifts. The publication is a dependable source of data for readers interested in the applications of nuclear magnetic resonance spectroscopy.

Product Details

ISBN-13:	9781483138596
Publisher:	Elsevier Science
Publication date:	10/22/2013
Sold by:	Barnes & Noble
Format:	eBook
Pages:	472
File size:	10 MB

Table of Contents

PART 1: An introduction to the theory and practice of nuclear magnetic resonance spectroscopy

Chapter 1: THEORY OF NUCLEAR MAGNETIC RESONANCE

Chapter 2: THE EXPERIMENTAL METHOD

PART 2: Theory of chemical effects in nuclear magnetic resonance spectroscopy

Chapter 3: TIME-DEPENDENT EFFECTS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

Chapter 4: THEORY OF THE CHEMICAL SHIFT

Chapter 5: THEORY OF SPIN-SPIN MULTIPLICITY

Chapter 6: THEORY AND APPLICATIONS OF MULTIPLE IRRADIATION

PART 3: Applications of the chemical shift

Chapter 7: GENERAL CONSIDERATIONS

Chapter 8: PROTONS BONDED TO NON-CYCLIC sp3 CARBON ATOMS

Chapter 9: PROTONS BONDED TO NON-AROMATIC sp2 CARBON ATOMS

Chapter 10: PROTONS BONDED TO sp CARBON ATOMS

Chapter 11: PROTONS BONDED TO sp3 CARBON ATOMS IN NON-AROMATIC CYCLIC STRUCTURES

Chapter 12: PROTONS BONDED TO AROMATIC AND HETEROCYCLIC CARBON ATOMS

Chapter 13: PROTONS BONDED TO ELEMENTS OTHER THAN CARBON

Chapter 14: STEREOCHEMISTRY AND THE CHEMICAL SHIFT

Chapter 15: CARBONIUM IONS, CARBANIONS AND RELATED SYSTEMS

PART 4: Spin-spin coupling

Chapter 16: INTRODUCTION TO SPIN-SPIN COUPLING

Chapter 17: GEMINAL INTERPROTON COUPLING

Chapter 18: VICINAL INTERPROTON COUPLING

Chapter 19: INTERPROTON COUPLING IN AROMATIC AND HETEROCYCLIC SYSTEMS

Chapter 20: LONG-RANGE INTERPROTON COUPLING

Chapter 21: COUPLING BETWEEN PROTONS AND OTHER NUCLEI1803

PART 5: Applications of time-dependent phenomena

Chapter 22: INTRODUCTION TO APPLICATIONS OF TIME-DEPENDENT PHENOMENA

Chapter 23: GENERAL APPLICATIONS

Chapter 24: INTERNAL ROTATION AND EQUIVALENCE OF NUCLEI

Chapter 25: TAUTOMERISM

REFERENCES

INDEX